1. Basic properties and characteristics of Li-ion batteries

1.6. Li-ion cell II

  • Temperature rise to critical values → electrolyte evaporation → internal short circuit → fire / explosion
  • Separator - prevents internal short circuit, porous, through for Li+.
  • Electrolyte applied to a thin separator.
  • Cylindrical cell - all these layers are rolled into a roll.
  • Electrons must not come into contact with the electrolyte → degradation of the electrolyte.
  • SEI (solid electrolyte interphase) - a layer preventing the contact of electrons with the electrolyte and its degradation
  • SEI is formed on the very first charge.
  • Li+ → electrolyte → Li+ + solvent molecules → reactions with graphite → SEI
  • About 5% of lithium is used to create SEI.
  • Current battery life: 3000 cycles, 10 years

  • R&D direction - replace graphite with Si
    • Increasing energy density
    • However, Si increases its volume during charging → possibly a combination of graphite and Si.





Chaofeng Liu1, Zachary G. Neale2 and Guozhong Cao: Understanding electrochemical potentials of cathode materials in rechargeable batteries, Materials Today, Volume 19, Number 2, Elsevier 2016